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Page 1

MATERIAL
SAFETY DATA SHEET

PAGE

1
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5

VALVTECT A
DIVISION OF

EMERGENCIES

KOP-COAT,
INC.

HEALTH/SPILLS......:
800-548-0489

3400 DUNDEE
ROAD

CHEMTREC
ASSISTANCE: 800-424-9300

NORTHBROOK

CHEMTREC
OUTSIDE US: 703-527-3887

IL

60062

CANUTEC............:
613-996-6666

VALVTECT A
DIVISION OF

PRODUCT
INFORMATION: 847-272-2278

OUTSIDE
USA........: 847-272-2278

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1 PRODUCT
IDENTIFICATION

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PRODUCT NAME:
BioGuard ULS

PRODUCT USE.:
Fuel Additive - Antimicrobial agent

APPEARANCE..:
Yellowish brown liquid

CAS NUMBER..:
Mixture

SYNONYMS....:
None

REVISION...:

1

DATE.......:
1/09/07

MSDS NUMBER:
BGDULS201

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2 HAZARDOUS
INGREDIENTS

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HAZARDOUS
COMPONENT

REG
AGENCY

PPM

NOTES

MG/M3

NOTES

1-Nitropropane

(None
established.)

CAS
NUMBER:108-03-2

PERCENT BY WGT:
5 TO 10

Morpholine
(skin)

ACGIH
TWA

20

71

CAS
NUMBER:110-91-8

NIOSH

20

70

PERCENT BY WGT:
5 TO 10 NIOSH-STEL

30

105

OSHA
STEL

30

105

OSHA
TWA

20

70

4-4-(2-Ethyl-2-nitroti-

(None
established.)

methylene
dimorpholine

CAS
NUMBER:1854-23-5

PERCENT BY WGT:
1 TO 5

4-(2-Nitrobutyl)morpho-

(None
established.)

line

CAS
NUMBER:2224-44-4

PERCENT BY WGT:
75 TO 80

Methylene
dimorpholine

(None
established.)

CAS
NUMBER:5625-90-1

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PRODUCT NAME:
BioGuard ULS

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5

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2 HAZARDOUS
INGREDIENTS

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HAZARDOUS
COMPONENT

REG
AGENCY

PPM

NOTES

MG/M3

NOTES

PERCENT BY
WGT: 5 TO 10

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3 HAZARDS
IDENTIFICATION

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EMERGENCY
OVERVIEW: DANGER! CORROSIVE. Harmful or fatal if swallowed, can
enter

lungs and
cause damage. Can cause skin and eye burns. Combustible
liquid/vapor.

EYES: May
cause severe eye irritation and eye burns if not rinsed from
eyes

promptly.
Symptoms may include stinging, tearing, redness, swelling of
eyes

and potential
corneal damage if not promptly rinsed from eyes.

SKIN: Short
single exposure may cause severe skin irritation. Prolonged or

repeated
exposure may cause skin burns. A single prolonged exposure may
result

in the
material being absorbed in harmful amounts. Skin contact may cause
an

allergic skin
reaction (sensitization) in susceptible individuals.

INHALATION:
Inhalation of aerosols or mists may cause respiratory tract

irritation.

INGESTION:
Single dose oral toxicity is considered to be low. Small
amounts

swallowed
incidental to normal handling operations are not likely to
cause

injury;
swallowing amounts larger than that may cause injury.

CHRONIC:
Repeated exposure did not produce systemic toxicity when applied
to

the skin of
rabbits and rats.

Individuals
with pre-existing disease in or a history of ailments involving
the

skin, eyes,
respiratory tract, liver, kidney, blood or central nervous
system

are at
agreater than normal risk of developing adverse effects when exposed
to

this
material.

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4 FIRST AID
MEASURES

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EYE CONTACT:
Immediately flush the eyes with lukewarm, gently flowing water
for

at least 20
minutes, while holding the eyelids open. Take care not to rinse

contaminated
water into the unaffected eye or face. Remove contact lenses,

if present,
after the first five minutes, then continue rinsing eye. Call a

poison control
center or doctor for treatment advice.

SKIN CONTACT:
Wash affected areas immediately with non-abrasive soap and

lukewarm water
for 15-20 minutes. Under running water, remove contaminated

clothing,
shoes, and leather goods (i.e. watchbands, belts). Call a
poison

control center
or doctor for treatment advice. Completely decontaminate

clothing,
shoes and leather goods before reuse or discard.

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PRODUCT NAME:
BioGuard ULS

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3
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5

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4 FIRST AID
MEASURES

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INHALATION:
Remove source of contamination or move victim to fresh air. If

breathing is
difficult, oxygen may be beneficial if administered by trained

personnel,
preferably on a doctor's advice. DO NOT allow victim to move
about

unnecessarily.
Symptoms of pulmonary edema may be delayed up to 48 hours after

exposure. Call
a poison control center or doctor for treatment advice.

INGESTION:
Call a poison control center or doctor immediately for
treatment

advice. Have
person rinse mouth thoroughly with water. DO NOT INDUCE
VOMITING.

Have person
drink 8-10 oz (240-300 mL) of water to dilute material in
stomach.

If milk is
available, it may be administered AFTER the water has been
given.

If vomiting
occurs naturally, have victim lean forward to reduce risk of

aspiration.
Repeat administration of water. Quickly transport person to

emergency care
facility.

NOTE TO
PHYSICIAN: Mucosal damage may contraindicate the use of gastric
lavage.

Pulmonary
aspiration hazard if swallowed. Treat symptomatically.

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5 FIRE
FIGHTING MEASURES

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FLASH POINT:
174 F

AUTOIGNITION
TEMPERATURE: No information found.

FLAMMABLE
LIMITS (% by volume/air)

Lower Limit:
No information found.

Upper Limit:
No information found.

EXTINGUISHING
MEDIA: Use dry chemical, carbon dioxide, foam or water spray
(fog)

FIRE FIGHTING
PROCEDURES: As in any fire, wear complete fire service
protective

equipment,
including full-face MSHA/NIOSH approved or equivalent
self-contained

breathing
apparatus. Use water to cool fire-exposed
container/structure/protect

personnel.
Toxic vapors may be given off in a fire. Contain run-off from
fire.

FIRE AND
EXPLOSION HAZARDS: When heated (fire conditions), can release
toxic

vapors. Closed
containers may explode when exposed to extreme heat (fire).

"Empty"
containers retain product residue (liquid and/or vapor) and can
be

dangerous. DO
NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR
EXPOSE

SUCH
CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES
OF

IGNITION; THEY
MAY EXPLODE AND CAUSE INJURY OR DEATH. Empty drums should be

completely
drained, properly bunged and promptly returned to a drum recon-

ditioner, or
disposed of properly.

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6 SPILL AND
LEAK PROCEDURES

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SMALL SPILL:
Stop the flow of material. Absorb with non-flammable suitable

absorbent such
as sand or earth. Scoop/shovel absorbed material into
container.

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PRODUCT NAME:
BioGuard ULS

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4
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5

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6 SPILL AND
LEAK PROCEDURES

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LARGE SPILL:
Dike and contain spill. Pump to storage or salvage vessels.

Contain
run-off from fire control and dilution water. Prevent run-off
to

sewers,
streams or other bodies of water. If run-off occurs, notify
proper

authorities
that a spill has occurred. Eliminate ALL sources of ignition.

Ventilate
area.

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7 HANDLING
AND STORAGE

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Handling
Procedures: Avoid skin contact with this material. Avoid eye
contact

with this
material. Avoid prolonged or repeated breathing of this
material.

Observe good
personal hygiene practices and recommended procedures. Wash

thoroughly
after handling. Use this product with adequate ventilation.

Storage
Procedures: Do not store near heat, sparks, open flame or
strong

oxidizing
agents. Do not store this material in open, unlabeled
containers.

Keep in a
closed, labeled container within a cool (well-shaded), dry,
ventilated

area. Protect
from physical damage. Empty containers retain product residue

(liquid or
vapor) and can be dangerous. Do not pressurize, cut, weld,
braze,

solder, drill,
grind or expose such containers to heat, flame, sparks, static

electricity,
or other sources of ignition; they may explode. Follow
appropriate

grounding
procedures, as applicable.

This product
should be stored between 10 to 35 C (50 to 97 F).

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8 EXPOSURE
CONTROLS/PERSONAL PROTECTION

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ENGINEERING
CONTROLS: Provide sufficient general / local exhaust ventilation
in

pattern/volume
to control inhalation exposures below current exposure limits
and

below
flammable vapor concentrations. Ventilation rates should be matched
to

use
conditions. Supplementary local exhaust ventilation may be needed in
poorly

ventilated
spaces, during spraying, heating or other non-routine
activities.

PERSONAL
PROTECTIVE EQUIPMENT:

EYE
PROTECTION: Industrial safety goggles and face sheild, as
neccesary.

HAND/SKIN
PROTECTION: Chemical resistant, flexible-type gloves

(neoprene,
nitrile or equal) to prevent contact. Gloves should be rinsed
and

removed
immediately after use. Wash hands after removing gloves. Use
protective

clothing
impervious to this material. Selection of specific items such
as

boots, apron,
or full body suit will depend on operation.

RESPIRATORY
PROTECTION: Respiratory protection may be necessary under
certain

use
conditions. A NIOSH-approved respirator should be selected on the basis
of

the form and
concentration of the contaminant.

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PRODUCT NAME:
BioGuard ULS

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5

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8 EXPOSURE
CONTROLS/PERSONAL PROTECTION

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OTHER:
Facilities utilizing this material should be equipped with an
eyewash

station and
safety shower. Remove contaminated clothing immediately, wash
skin

area with soap
and water, and launder clothes before reuse. Items which cannot

be
decontaminated such as shoes, belts and watchbands, should be removed
and

destroyed.

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9 PHYSICAL
AND CHEMICAL PROPERTIES

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Weight Per
Gallon (lbs):

9.174

% VOL by
Weight.: Not determined

Vapor
Density.: 10 Max (air=1)

Boiling
Point...: Not determined

Vapor
Pressure: 30 mmHg @90 C

Evaporation
Rate: Not determined

pH............: 9.5
- 10.0

Specific
Gravity: 1.1 @ 25 C

Solubility In
Water: Not determined

Viscosity.......:
Not determined

VOC
Content................: Not determined

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10 STABILITY
AND REACTIVITY DATA

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STABILITY:
Stable under recommended storage conditions. Unstable at
elevated

temperatures.

HAZARDOUS
POLYMERIZATION: Will not occur.

INCOMPATIBILITY:
Avoid contact with oxidizing and acidic materials.

HAZARDOUS
DECOMPOSITION PRODUCT(S): Thermal decomposition may release
toxic

gases
depending upon temperature, air supply and the presence of
other

materials.

CONDITIONS TO
AVOID: Avoid temperatures above 35C (97F). Can crytallize.

Dissolve
crystals before use by warming and mixing. Avoid temperatures
below

10C (50F).
Potentially violent decomposition can cause pressure in closed

systems.
Pressure build-up can be rapid.

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11
TOXICOLOGICAL INFORMATION

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ORAL LD50
(rat): 620 mg/kg

DERMAL LD50
(rabbit): 420 mg/kg

INHALATION
LC50 (rat): 746 mg/l

MUTAGENICITY:
In vitro mutagenicity studies were negative.

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12 ECOLOGICAL
INFORMATION

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This product
is toxic to fish and wildlife. Do not contaminate water by
cleaning

equipment or
disposal of waste. Do not discharge effluent containing
this

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PRODUCT NAME:
BioGuard ULS

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12 ECOLOGICAL
INFORMATION

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product into
lakes, streams, ponds, estuaries, oceans or other waters unless
in

accordance
with the requirements of a National Pollutant Discharge
Elimination

System (NPDES)
permit and the permitting authority has been notified in
writing

prior to
discharge. For guidance, contact your Regional Office of the

Environmental
Protection Agency.

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13 DISPOSAL
CONSIDERATIONS

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Do not
contaminate water, food, or feed by storage or disposal.
Pesticide

wastes are
toxic. Improper disposal of excess pesticide, spray mixture, or

rinsate is a
violation of federal law. If these wastes cannot be disposed of
by

use according
to label instructions, contact your State Pesticide or Environ-

mental Control
Agency, or the hazardous waste representative at the nearest
EPA

regional
office for guidance.

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14
TRANSPORTATION INFORMATION

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DOT PROPER
SHIPPING NAME:

UN3142,
Disinfectant liquid, Toxic, n.o.s. (4-(2-Nitrobutyl)morpholine)

DOT HAZARD
CLASS: 6.1 Packing Group III

LABEL:
Toxic

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15 REGULATORY
INFORMATION

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EPA
REGISTRATION NUMBER: 464-659-60061

Ultra Low
Sulfur Diesel Additives: The sulfur content of this Diesel Fuel

Additive does
not exceed 15 parts per million (ppm).

References:
Code of Federal Regulations Title 40 Part 80 - EPA 2006
Regulation

of Fuels and
Fuel Additives, and EPA document EPA40-F-05-013.

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16 OTHER
INFORMATION

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NOTICE: This
document is generated for the purpose of distributing health,

safety and
environmental data. The information on this MSDS was obtained
from

sources which
we believe are reliable. However, the information is provided

without any
warranty, expressed or Implied, regarding correctness. Some

information
presented and conclusions drawn herein are from sources other
than

direct test
data on the substance itself. Kop-Coat makes no warranty with

respect
thereto and disclaims all liability from reliance
thereon.

Page 7

PRODUCT NAME:
BioGuard ULS

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7
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5

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16 OTHER
INFORMATION

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PREPARED BY:
Manager of Health, Safety and Environmental
Affairs.